Evidence of β-MoO3 formation during thermal treatment of silica-supported 12-molybdophosphoric acid catalysts

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Abstract

Unsupported and silica-supported H3PMo12O 40 catalysts show a wide temperature range for decomposition on thermal treatment allowing the formation of monoclinic β-MoO3 (characterized by Raman spectroscopy and X-ray powder diffraction); this new supported phase leads specifically to dimethoxymethane in the methanol oxidation reaction.

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Fournier, M., Aouissi, A., & Rocchiccioli-Deltcheff, C. (1994). Evidence of β-MoO3 formation during thermal treatment of silica-supported 12-molybdophosphoric acid catalysts. Journal of the Chemical Society, Chemical Communications, (3), 307–308. https://doi.org/10.1039/C39940000307

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