Abstract
The structure transformation of Mg-CUK-1 due to the confinement of H2O molecules was investigated. Powder X-ray diffraction (PXRD) patterns were collected at different H2O loadings and the cell parameters of the H2O-loaded Mg-CUK-1 material were determined by the Le Bail strategy refinements. A bottleneck effect was observed when one hydrogen-bonded H2O molecule per unit cell (18% relative humidity (RH) was confined within Mg-CUK-1, confirming the increase in the CO2 capture for Mg-CUK-1.
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Sánchez-González, E., Flores, J. G., Flores-Reyes, J. C., Morales-Salazar, I., Blanco-Carapia, R. E., Rincón-Guevara, M. A., … Ibarra, I. A. (2020). Bottleneck effect explained by Le Bail Refinements: Structure transformation of Mg-CUK-1 by confining H2O molecules. Materials, 13(8). https://doi.org/10.3390/MA13081840
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