Abstract
The synthesis of a hitherto unknown 6 : 5 phase in the quasi-binary system RbCl/PbCl2 and its structure determination is reported. The compound Rb6Pb5Cl16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature of the structure is a statistical distribution of Rb and Pb at one of the cation sites with a ratio of 1 : 3 as defined by electroneutrality. There is no evidence for symmetry reduction by ordering.
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Beck, H. P., Schramm, M., Haberkorn, R., Dinnebier, R., & Stephens, P. W. (1998). Synthesis and crystal structure of Rb6Pb5Cl16. Zeitschrift Fur Anorganische Und Allgemeine Chemie, 624(3), 393–398. https://doi.org/10.1002/(SICI)1521-3749(199803)624:3<393::AID-ZAAC393>3.0.CO;2-V
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