Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

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Abstract

A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe-Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic results are presented.

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Hettmanczyk, L., Manck, S., Hoyer, C., Hohloch, S., & Sarkar, B. (2015). Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis. Chemical Communications, 51(54), 10949–10952. https://doi.org/10.1039/c5cc01578b

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