Adhesion of electrospun poly(Acrylonitrile) nanofibers on conductive and isolating foil substrates

Abstract

Electrospinning can be used to prepare nanofibers from various polymers and polymer blends. The adhesion of nanofibers to the substrates on which they are electrospun varies greatly with the substrate material and structure. In some cases, good adhesion is desired to produce sandwich structures by electrospinning one material directly onto another. This is the case, e.g., with dye‐sensitized solar cells (DSSCs). While both pure foil DSSCs and pure electrospun DSSCs have been examined, a combination of both technologies can be used to combine their advantages, e.g., the lateral strength of foils with the large surface‐to‐volume ratio of electrospun nanofibers. Here, we investigate the morphology and adhesion of electrospun nanofibers on different foil substrates containing materials commonly used in DSSCs, such as graphite, poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) or TiO2. The results show that the foil material strongly influences the adhesion, while a plasma pretreatment of the foils showed no significant effect. Moreover, it is well known that conductive substrates can alter the morphology of nanofiber mats, both at microscopic and macroscopic levels. However, these effects could not be observed in the current study.