Preparation and characterization of hydroxo-zinc(II) complex surrounded with hydrogen bonding and hydrophobic interaction groups. A structural/functional model of carbonic anhydrases

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Abstract

A novel Zn(II)-OH complex surrounded with hydrogen bonding and hydrophobic interaction groups has been prepared as a structural/functional model of carbonic anhydrases, and characterized by X-ray structure analysis and ESIMS and 1H- and 13C-NMR spectroscopies. The complex has been found to exhibit a reversible binding of CO2.

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Yamaguchi, S., Tokairin, I., Wakita, Y., Funahashi, Y., Jitsukawa, K., & Masuda, H. (2003). Preparation and characterization of hydroxo-zinc(II) complex surrounded with hydrogen bonding and hydrophobic interaction groups. A structural/functional model of carbonic anhydrases. Chemistry Letters, 32(4), 406–408. https://doi.org/10.1246/cl.2003.406

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