Polymer-to-carbon conversion: From nature to technology

Abstract

Glassy carbon is derived from synthetic organic polymers that undergo the process of coking during their pyrolysis. Polymer-to-carbon conversion (hereafter referred to as PolyCar) also takes place in nature, and is indeed responsible for the formation of various naturally occurring carbon allotropes. In the last few decades the PolyCar concept has been utilized in technological applications, i.e., specific polymers are patterned into the desired shapes and intentionally converted into carbon by a controlled heat-treatment. Device fabrication using glassy carbon is an excellent example of the use of the PolyCar process in technology, which has rapidly progressed from conventional to micro- and nanomanufacturing. While the technique itself is simple, one must have a good understanding of the carbonization mechanism of the polymer, which in turn determines whether or not the resulting material will be glassy carbon. Publications that comprise this special issue shed light on several aspects of the formation, properties and performance of glassy carbon in the cutting-edge technological applications. The results of detailed material characterization pertaining to two important research areas, namely neural electrodes and precision glass molding, are presented as examples. I hope that the readers will enjoy as well as benefit from this collection.