Controlled release of a dendritically encapsulated template molecule

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Abstract

Supramolecular dendrimers have been assembled in solution by using the interactions between dendritic branches functionalized with [18]crown-6 and a bis-ammonium cation as a template (see scheme). Disassembly is triggered by the addition of K+ ions, which enables controlled release of the encapsulated template.

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Dykes, G. M., Smith, D. K., & Seeley, G. J. (2002). Controlled release of a dendritically encapsulated template molecule. Angewandte Chemie - International Edition, 41(17), 3254–3257. https://doi.org/10.1002/1521-3773(20020902)41:17<3254::AID-ANIE3254>3.0.CO;2-4

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