Abstract
The spiroacetal [C(9)-C(20)] fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113, were prepared from a known bromo alcohol derived from (S)-citronellal, using thermodynamically controlled iodolactonization and spiroacetalization as the key steps.
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Sakauchi, H., Higashi, E., Shimizu, Y., Kojima, M., Asamitsu, Y., Kuwahara, S., … Kiyota, H. (2015). Synthesis of the spiroacetal fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113. Heterocyclic Communications, 21(6), 337–343. https://doi.org/10.1515/hc-2015-0193
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