Abstract
The participation of silicon d orbitals in the siloxane bonds in H3COSiH3, H3SiOSiH3, and H3SiO-OSiH3 has been investigated by ab initio termination of geometric and electronic structures of these molecules, (p-d)x bonding in the Si-0 bond was found to be of minor importance, while the ionic character of the bond is much higher than that estimated from electronegativities. © 1980, American Chemical Society. All rights reserved.
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CITATION STYLE
APA
Oberhammer, H., & Boggs, J. E. (1980). Importance of (p-d)π Bonding in the Siloxane Bond. Journal of the American Chemical Society, 102(24), 7241–7244. https://doi.org/10.1021/ja00544a011
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