Uncertainty budgets of major ozone absorption cross sections used in UV remote sensing applications

Abstract

Detailed uncertainty budgets of three major ultraviolet (UV) ozone absorption cross-section datasets that are used in remote sensing application are provided and discussed. The datasets are Bass–Paur (BP), Brion–Daumont–Malicet (BDM), and the more recent Serdyuchenko–Gorshelev (SG). For most remote sensing application the temperature dependence of the Huggins ozone band is described by a quadratic polynomial in temperature (Bass–Paur parameterization) by applying a regression to the cross-section data measured at selected atmospherically relevant temperatures. For traceability of atmospheric ozone measurements, uncertainties from the laboratory measurements as well as from the temperature parameterization of the ozone cross-section data are needed as input for detailed uncertainty calculation of atmospheric ozone measurements. In this paper the uncertainty budgets of the three major ozone cross-section datasets are summarized from the original literature. The quadratic temperature dependence of the cross-section datasets is investigated. Combined uncertainty budgets is provided for all datasets based upon Monte Carlo simulation that includes uncertainties from the laboratory measurements as well as uncertainties from the temperature parameterization. Between 300 and 330ĝ€nm both BDM and SG have an overall uncertainty of 1.5ĝ€%, while BP has a somewhat larger uncertainty of 2.1ĝ€%. At temperatures below about 215ĝ€K, uncertainties in the BDM data increase more strongly than the others due to the lack of very low temperature laboratory measurements (lowest temperature of BDM available is 218ĝ€K).