Comparative studies on superconductivity in Cr3Ru compounds with bcc and A15 structures

Abstract

Chromium (Cr) is a transition metal element with 3d orbital electrons. In most compounds containing Cr, due to the correlation effect, twofold features, namely localization and itinerancy are expected. The localization gives rise to a magnetic moment, while the latter exhibits as the effective coherent weight for conductivity. Here we report the physical properties of Cr3Ru compounds with body-centered cubic (bcc) and A15 structures by using multiple experimental tools. The resistivity measurements show sharp superconducting transitions at T c = 2.77 K and T c = 3.37 K for the bcc and A15 structures, respectively. A high residual resistivity exists in both phases. Magnetization measurements also show rather narrow superconducting transitions, with a clear hump feature in the intermediate temperature region (about 150 K), which may be ascribed to the remaining antiferromagnetic spin fluctuations. A pronounced second peak effect has been observed in magnetization hysteresis loops in the superconducting state only for samples with bcc structure. The specific heat coefficient reveals a clear jump at critical temperatures ( T c ). We find that s-wave gaps can be adopted to fit the low temperature specific heat data of both samples yielding ratios of 2 Δ / k B T c about 3.6, indicating a moderate pairing strength. Interestingly, the Wilson ratios R W = A χ 0 / γ n are 3.81 and 3.62 for the bcc and A15 phases, suggesting a moderate correlation effect of conducting electrons in the normal state. Besides, for samples with A15 structure, another specific heat anomaly occurs at about 0.85 K and is sensitive to magnetic fields. In addition, by applying high pressures, both systems will exhibit an enhancement of T c with a rate of about 0.019 K GPa−1 and 0.013 K GPa−1 for the bcc and A15 phases, respectively. Our combinatory results point to unusual behavior of both superconducting and normal states in these two Cr based alloys.