Abstract
We report a highly efficient and 100% atom economic synthesis of methyl acrylate and acetic acid via gas phase pyrolysis of methyl 3-acetoxypropionate at 600 °C. The latter can be produced in a single step from methyl levulinate, a side product of Avantium's FDCA process.
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El Ouahabi, F., Polyakov, M., Van Klink, G. P. M., Wohlrab, S., Tin, S., & De Vries, J. G. (2020). Highly Efficient and Atom Economic Route for the Production of Methyl Acrylate and Acetic Acid from a Biorefinery Side Stream. ACS Sustainable Chemistry and Engineering, 8(4), 1705–1708. https://doi.org/10.1021/acssuschemeng.9b06215
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