Synthesis and X-ray structural characterization of the (chlorochalcogeno)phosphonium cations R2R′PSCl+ and R2R′PSeCl+ as their AuCl4− salts

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Abstract

Phosphine chalcogenides R2R′PE react with (tht)AuCl to form complexes of the type R2R′PEAuCl (E = S, Se); stepwise oxidation with PhICl2 leads first to R2R′PEAuCl3 and then to the (chlorochalcogeno)phosphonium salts R2R′PECl+AuCl4−. © 2013 The Royal Society of Chemistry.

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Upmann, D., & Jones, P. G. (2013). Synthesis and X-ray structural characterization of the (chlorochalcogeno)phosphonium cations R2R′PSCl+ and R2R′PSeCl+ as their AuCl4− salts. Journal of the Chemical Society. Dalton Transactions, 42(21), 7526–7528. https://doi.org/10.1039/c3dt50777g

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