The Long-Time Self-Diffusivity in Concentrated Colloidal Dispersions

Abstract

The long-time self-diffusivity in concentrated colloidal dispersions is determined from a consideration of the temporal decay of density fluctuations. For hydrodynamically interacting Brownian particles the long-time self-diffusivity, Ds∞, is shown to be expressible as the product of the hydrodynamically determined short-time self-diffusivity, Ds0(Φ), and a contribution that depends on the distortion of the equilibrium structure caused by a diffusing particle. An argument is advanced to show that as maximum packing is approached the long-time self-diffusivity scales as Ds∞~ Ds0(Φ)/g(2;Φ), whereg(2;Φ), g(2;is the value of the equilibrium radial-distribution function at contact and Φ is the volume fraction of interest. This result predicts that the long-time self-diffusivity vanishes quadratically at random close packing, a), the same formula applies with the short-time self-diffusivity still determined by hydrodynamic interactions at the true or ‘hydrodynamic’ volume fraction ∞, but the structural deformation and equilibrium radial-distribution function are now determined by the 4 thermodynamic’ volume fraction Φbbased on the length b. When b> a, the long-time self-diffusivity vanishes linearly at random close packing based on the ‘thermodynamic’ volume fraction Φbm. This change in behaviour occurs because the true or ‘hydrodynamic’ volume fraction is so low that the short-time self-diffusivity is given by its infinite-dilution value Φ0. It is also shown that the temporal transition from short- to long-time diffusive behaviour is inversely proportional to the dynamic viscosity and is a universal function for all volume fractions when time is non-dimensionalized by a2/Ds0(Φ)(∞). © 1994, Cambridge University Press. All rights reserved.