Fluorescent perylene derivative functionalized titanium oxide gel for sensitive and portable ascorbic acid detection

Abstract

An inorganic titanium oxide (TiO) gel sensor was demonstrated for convenient detection of ascorbic acid (AA). It is composed of TiO (PI-TiO) functionalized with a perylene diimide derivative containing carboxylic groups as a new soft dopant material. A traditional solvothermal reaction is adopted to prepare the PI-TiO composite, which exhibits a different spectrum according to the reaction time. The final gel possesses a strong chelating affinity with AA molecules, in which phenol hydroxyl groups are shown to compete with those already present in PI. We further utilize the functionalized gel to prepare a series of films with a simple and portable AA response. A visual colour variation can be recognized by the naked eye, together with obvious fluorescence changes for selective and sensitive AA detection. Finally, the as-prepared gel film displays good stability and reproducibility for real sample responses with satisfying results.