The Role of Non-Metallic and Metalloid Elements on the Electrocatalytic Activity of Cobalt and Nickel Catalysts for the Oxygen Evolution Reaction

Abstract

Compounds and alloys of cobalt and nickel with some nonmetals (N, P, S, Se) and metalloids (C, B, C, As and Te) have emerged as very promising noble metal-free pre-catalysts for the oxygen evolution reaction (OER) in alkaline electrolytes. However, the exact role played by the non-metals and metalloids in promoting the OER is not well understood. A holistic understanding of the origin of the OER activity enhancement in these compounds is vital for their exploitation as models to inspire knowledge-guided design of improved OER catalysts. In this review, we elucidate the factors that govern the activity and stability of OER catalysts derived from MX compounds (M=Co or Ni, and X=nonmetal or metalloid), including the impact of surface electronic structure, M : X stoichiometry, material composition, structure and crystallinity, as well as the role of oxoanions on the properties of the electrochemical double layer and interaction energies of the reaction intermediates. Finally, we outline a few perspectives and research directions towards a deeper understanding of the role of the nonmetal and metalloid elements and design of improved OER catalysts.