Abstract
A perfect pair: Silanediols are effective catalysts for the addition of silyl ketene acetals to N-acylisoquinolinium ions. Importantly, this is the first example of a silanediol plausibly participating in anion-binding catalysis, a relatively new direction in the field of hydrogen-bond-donor catalysis. The chiral, enantiopure C2-symmetric silanediol 1 catalyzes enantioselective transformations. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Schafer, A. G., Wieting, J. M., Fisher, T. J., & Mattson, A. E. (2013). Chiral silanediols in anion-binding catalysis. Angewandte Chemie - International Edition, 52(43), 11321–11324. https://doi.org/10.1002/anie.201305496
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