Abstract
The SF5Cl radical addition on unsaturated compounds was performed using an air-stable amine-borane complex as the radical initiator. This method showed to be complementary to the classic Et3B-mediated SF5Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.
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APA
Gilbert, A., Langowski, P., Delgado, M., Chabaud, L., Pucheault, M., & Paquin, J. F. (2020). Amine-borane complex-initiated SF5Cl radical addition on alkenes and alkynes. Beilstein Journal of Organic Chemistry, 16, 3069–3077. https://doi.org/10.3762/BJOC.16.256
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