Alkene to carbyne: Tandem lewis acid activation and dehydrogenation of a molybdenum ethylene complex

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Abstract

Carbyne formation: Treatment of a molybdenum ethylene complex with B(C 6F5)3 induces ditopic activation of an ethylene ligand and acceptor-assisted ethane elimination to generate a novel type of zwitterionic carbyne complex (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Stennett, T. E., Haddow, M. F., & Wass, D. F. (2013). Alkene to carbyne: Tandem lewis acid activation and dehydrogenation of a molybdenum ethylene complex. Angewandte Chemie - International Edition, 52(43), 11356–11359. https://doi.org/10.1002/anie.201305233

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