ASSOCIATION OF CERIC IONS WITH SULPHATE (A SPECTRAL STUDY)

  • Hardwick T
  • Robertson E
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Abstract

Ceric ion has been shown to associate with sulphate ion to form successively Ce(SO 4 ++ , Ce(SO 4 ) 2 , and Ce(SO 4 ) 3 − . The association constants relating these species have been determined at 25 °C. The molar extinction coefficients of each associated complex have been found between 395 and 430 mμ. Migration experiments bear out the results qualitatively.

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Hardwick, T. J., & Robertson, E. (1951). ASSOCIATION OF CERIC IONS WITH SULPHATE (A SPECTRAL STUDY). Canadian Journal of Chemistry, 29(10), 828–837. https://doi.org/10.1139/v51-095

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