Abstract
In the title compound, C26H23N5O 2S, an intramolecular N -H⋯O interaction generates an S(6) ring. The essentially planar S(6) and pyrazole rings [maximum deviations = -0.0270 (14) and 0.0195 (15) Å, respectively] are nearly coplanar, making a dihedral angle of 3.94 (6)°. The S(6) ring makes dihedral angles of 23.79 (6), 78.53 (6) and 67.91 (6)° with the pyrazolone ring, the pyrazole ring and the benzene ring of antipyrine, respectively. The structure exhibits a thienylring flip disorder with occupancy factors in the ratio 0.82:0.18.
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CITATION STYLE
Zhu, H., Ban, L., Zhang, P., Zhao, X., & Ren, J. (2011). 1,5-Dimethyl-4-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene) (thiophen-2-yl)methyl]amino}-2-phenyl-1H-pyrazol-3(2H)-one. Acta Crystallographica Section E: Structure Reports Online, 67(2). https://doi.org/10.1107/S1600536811002467
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