The influence of alkali metal cations on the rate of the Fe(CN)64-/Fe(CN)63- electrode process

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Abstract

The rate of the hexacyanoferrate redox system shows a first order dependence on the concentration of the cationic component of the supporting electrolyte. The catalytic influence of the alkali metal cations on the electrode process increases in the order Li+

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Peter, L. M., Dürr, W., Bindra, P., & Gerischer, H. (1976). The influence of alkali metal cations on the rate of the Fe(CN)64-/Fe(CN)63- electrode process. Journal of Electroanalytical Chemistry, 71(1), 31–50. https://doi.org/10.1016/S0022-0728(76)80288-4

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