Measurement of the hydrophobic force in a soft matter system

Abstract

The hydrophobic attraction describes the well-known tendency for nonpolar molecules and surfaces to agglomerate in water, controlled by the reorganization of intervening water molecules to minimize disruption to their hydrogen bonding network. Measurements of the attraction between chemically hydrophobised solid surfaces have reported ranges varying from tens to hundreds of nanometers, all attributed to hydrophobic forces. Here, by studying the interaction between two hydrophobic oil drops in water under well-controlled conditions where all known surface forces are suppressed, we observe only a strong, short-ranged attraction with an exponential decay length of 0.30 ± 0.03 nm - comparable to molecular correlations of water molecules. This attraction is implicated in a range of fundamental phenomena from self-assembled monolayer formation to the action of membrane proteins and nonstick surface coatings. © 2013 American Chemical Society.