High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide

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Abstract

A green gold-cluster, Au30S(StBu)18, was successfully prepared in high yield and crystallographically characterized. Each cluster consists of an Au22 core capped by a mixed layer of staple Au-thiolate units, bridging thiolates and a μ3-S2−. © The Partner Organisations 2014.

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Yang, H., Wang, Y., Edwards, A. J., Yan, J., & Zheng, N. (2014). High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide. Chemical Communications, 50(92), 14325–14327. https://doi.org/10.1039/c4cc01773k

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