Tungsten-mediated syntheses, skeletal rearrangement and synthetic applications of η1-2,5-dihydro-3-furanyl rings

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Abstract

The syntheses, acid-catalysed rearrangements and demetallation chemistry of CpW(CO)3(η1-C=CR-CHR1-O-CH2) (R = CHCH2, C≡CPh; R1 = alkyl, phenyl; Cp = C 5H5) are reported, and their synthetic-utility in organic reactions is demonstrated.

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Cheng, M. H., Yang, G. M., Chow, J. F., Lee, G. H., Peng, S. M., & Liu, R. S. (1992). Tungsten-mediated syntheses, skeletal rearrangement and synthetic applications of η1-2,5-dihydro-3-furanyl rings. Journal of the Chemical Society, Chemical Communications, (13), 934–936. https://doi.org/10.1039/C39920000934

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