Adsorption of nicotine on different zeolite types, from aqueous solutions

Abstract

The plant alkaloid, nicotine, is a strongly toxic heterocyclic compound: the lethal dose for an adult human being (40-60 mg) is importantly lower in comparison with the other known poisons such as arsenic or strychni?ne. Cigarettes represent "the most toxic and addictive form of nicotine". Besides the negative effects of nicotine on public health produced by self-administration, recently another potentially very dangerous effect has been recognized: because of its miscibility with water, nicotine can be found in industrial wastewaters, and consequently, in groundwater. Therefore, the problem of nicotine removal from aqueous solutions has became an interesting topic. In this work, the removal of nicotine has been probed by adsorption on solid materials. Adsorption of nicotine on different zeolites (clinoptilolite, ZSM-5 and ? zeolite) and on activated carbon was investigated from aqueous solutions, at 298 K. The obtained results are presented as adsorption isotherms: the amount of adsorbed nicotine as a function of equilibrium concentration. These data were obtained from the residual amount of nicotine in the aqueous phase, by the use of UV spectroscopy. The highest amounts of adsorbed nicotine was found for activated carbon and p zeolite (~ mmol?g-1). The attempt to modify the adsorption properties of ZSM-5 zeolite has been also done: ZSM-5 was modified by ion-exchange with VIII group metal (Cu2+ and Fe3+). In addition, the adsorption of nicotine on ZSM-5 zeolite with different Si/Al ratios has been done. It has been noticed that ion-exchange did not improve the adsorption possibilities, while the adsorption was importantly lower in the case of higher silicon content in ZMS-5 structure. 13C NMR spectra were collected for suspensions formed of solid adsorbent and aqueous solution of nicotine; in this way, the part of nicotine molecule which is most probably connected with the adsorbent was recognized.U ovom radu ispitivana je adsorpcija nikotina iz vodenih rastvora na razlicitim zeolitima (klinoptilolitu, ZSM-5 i ? zeolitu) kao i na aktivnom uglju visoke specificne povrsine; na 298K. Dobijeni rezultati prikazani su u formi adsorpcionih izotermi: kolicina adsorbovanog nikotina u funkciji od ravnoteznih koncentracija nikotina. Ovi podaci dobijeni su iz odredjivanja kolicine nikotina preostale u vodenoj fazi, metodom UV spektroskopije. Najvece kolicine adsorbovanog nikotina utvrdjene su na aktivnom uglju i ? zeolitu (~ mmol/g). Iz 13C NMR spektara snimljenih iz suspenzije: cvrsti adsorbent-vodeni rastvor nikotina, utvrdjen je atom ugljenika preko koga se molekul nikotina najverovatnije vezuje sa povrsinama zeolita.