State of Manganese in the Photosynthetic Apparatus. 1. Extended X-ray Absorption Fine Structure Studies on Chloroplasts and Di-µ-oxe-Bridged Dimanganese Model Compounds

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Abstract

Extended X-ray absorption fine structure studies on the manganese contained in spinach chloroplasts and on certain di-µ-oxo-bridged manganese dimers of the form (X2Mn)O2(MnX2) (X = 2,2'-bipyridine and 1,10-phenanthroline) are reported. From these studies, the manganese associated with photosynthetic oxygen evolution is suggested to occur as a bridged transition-metal dimer with most likely another manganese. Extensive details on the analysis are included. © 1981, American Chemical Society. All rights reserved.

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Kirby, J. A., Robertson, A. S., Smith, J. P., Thompson, A. C., Cooper, S. R., & Klein, M. P. (1981). State of Manganese in the Photosynthetic Apparatus. 1. Extended X-ray Absorption Fine Structure Studies on Chloroplasts and Di-µ-oxe-Bridged Dimanganese Model Compounds. Journal of the American Chemical Society, 103(18), 5529–5537. https://doi.org/10.1021/ja00408a042

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