A copper-mediated oxidative difluoromethylation of terminal alkynes using nucleophilic TMSCF2H in the presence of an oxidant 9,10-phenanthraquinone was developed. This reaction provided a direct and efficient method for preparation of difluoromethylated alkynes.
CITATION STYLE
Zhu, S. Q., Xu, X. H., & Qing, F. L. (2015). Copper-mediated oxidative difluoromethylation of terminal alkynes with TMSCF2H. Organic Chemistry Frontiers, 2(9), 1022–1025. https://doi.org/10.1039/c5qo00186b
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