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Modulation of the reactivity profile of IBX by ligand complexation: Ambient temperature dehydrogenation of aldehydes and ketones to α,β-unsaturated carbonyl compounds

Angewandte Chemie - International Edition (2002) 41(6) 993-996
DOI: 10.1002/1521-3773(20020315)41:6<993::AID-ANIE993>3.0.CO;2-U
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Abstract

The reactivity profile of IBX can be altered by complexation with various ligands (e. g. 1-4). A new complex, IBX·MPO, is a remarkably effective oxidant and allows the room-temperature dehydrogenation of carbonyl compounds, for example, the formation of cyclooctenones 6 and 7 from cyclooctanone 5. IBX = iodoxybenzoic acid; MPO = 4-methoxypyridine-N-oxide.

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Nicolaou, K. C., Montagnon, T., & Baran, P. S. (2002). Modulation of the reactivity profile of IBX by ligand complexation: Ambient temperature dehydrogenation of aldehydes and ketones to α,β-unsaturated carbonyl compounds. Angewandte Chemie - International Edition, 41(6), 993–996. https://doi.org/10.1002/1521-3773(20020315)41:6<993::AID-ANIE993>3.0.CO;2-U

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