Phase transformation and intense 2.7 μm emission from Er3+ Doped YF3/YOF submicron-crystals

Abstract

Yttrium fluoride YF3:Er3+ and yttrium oxyfluoride YOF:Er3+ submicron-crystals with mid-infrared fluorescent emissions were synthesized for the first time. The rhombohedral phase YOF submicron-crystals were synthesized by the crystalline phase transformation from pure orthorhombic YF3 submicron-crystals, which were prepared by co-precipitation method. The composition and morphology were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM), which showed that submicron-crystals were quasi-spherical with the particle size of ∼400 nm. A novel formation mechanism of YOF submicron-crystals was proposed. Photoluminescence (PL) spectra indicated the 2.7 μm emission of Er3+ has remarkably enhanced with the increase of Er3+ doping concentration, and a novel dynamic circulatory energy transfer mechanism was proposed. Fourier transform infrared spectra (FTIR) were used to demonstrate the change of hydroxyl content. These oxyfluoride submicron-crystals provide a new material for nano/submicron- crystals-glass composites, and open a brand new field for the realization of mid-infrared micro/nano-lasers.