Mechanical Properties and Modification Mechanism of Thermosetting Polyurethane-Modified Asphalt

Abstract

To study the mechanical properties and modification mechanism of thermosetting polyurethane (PU)-modified asphalt, the effects of polyurethane dosage on the workability of polyurethane-modified asphalt were analyzed by means of rotational viscosity tests. The mechanical properties of polyurethane-modified asphalt with different polyurethane dosages were explored using tensile tests and dynamic mechanical analysis (DMA). In addition, the thermodynamic behavior and micromorphology of polyurethane-modified asphalt were also thoroughly investigated using the test results of differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The results showed that PU obtained the optimum workability when the polyurethane dose was 50%: at 120 min, its rotational viscosity was 1005 cp, which was lower than 2800 cp (40% PU) and 760 cp (60% PU). Additionally, the results of fracture elongation and fracture strength indicated that the PU-modified asphalt had good flexibility and strength. Compared with base asphalt, the tensile strength of 50% PU-modified asphalt increased by 509%, which was significantly higher than 157% (40% PU) and more balanced than 897% (60% PU) in terms of strength and flexibility. Added PU can significantly improve the elasticity of asphalt at high temperatures, while increasing the proportion of asphalt adhesive components, enhancing the deformation ability and temperature stability of asphalt. As the dose of PU increases, the interface between asphalt and PU blended more fully, and the surface became smoother. When the dose of PU was 50% or more, the interface between asphalt and PU was well integrated with a smooth and flat surface, forming a more uniform and stable cross-linked network structure.