N-(Adamantan-1-yl)-1,2,3,4-tetrahydroisoquinoline-2-carbothioamide

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Abstract

In the title compound, C20H26N2S, the N-containing six-membered ring adopts a boat conformation and the dihedral angle between the thiocarbamide group and the benzene ring is 49.67 (9)°. An intramolecular C-H⋯S hydrogen bond generates an S(6) ring motif. The N-H group is sterically hindered and there are no significant intermolecular interactions beyond van der Waals contacts.

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El-Emam, A. A., Al-Abdullah, E. S., Al-Tuwaijri, H. M., Chidan Kumar, C. S., & Fun, H. K. (2013). N-(Adamantan-1-yl)-1,2,3,4-tetrahydroisoquinoline-2-carbothioamide. Acta Crystallographica Section E: Structure Reports Online, 69(12). https://doi.org/10.1107/S1600536813031516

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