Fluorine-enabled cationic gold catalysis: Functionalized hydration of alkynes

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Abstract

Fluorine makes it possible: A cationic fluorine-gold species generated by fluorination of a low-valence gold complex mediates the "functionalized hydration" of alkynes. A triple bond is used to install a carbonyl group and two new bonds on the a-carbon atom, all occurring in one pot, under mild conditions and in very good. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Wang, W., Jasinski, J., Hammond, G. B., & Xu, B. (2010). Fluorine-enabled cationic gold catalysis: Functionalized hydration of alkynes. Angewandte Chemie - International Edition, 49(40), 7247–7252. https://doi.org/10.1002/anie.201003593

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