Oxygen atom transfer in the photocatalytic oxidation of alcohols by tio2: Oxygen isotope studies

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Abstract

An uninvited guest: In the photocatalytic oxidation of alcohols to their corresponding aldehydes or ketones using TiO2 in organic solvents, such as benzotrifluoride (BTF), an oxygen atom transfer from the dioxygen to the α-carbon atom of the alcohol dominates the reaction process. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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Zhang, M., Wang, Q., Chen, C., Zang, L., Ma, W., & Zhao, J. (2009). Oxygen atom transfer in the photocatalytic oxidation of alcohols by tio2: Oxygen isotope studies. Angewandte Chemie - International Edition, 48(33), 6081–6084. https://doi.org/10.1002/anie.200900322

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