Abstract
It has been shown that 1-hydrosilatrane reacts with o-difluoromethpxybenzaldoxime in refluxing xylene without any catalyst affording a new type of silatranes - iminoxysilatrane. The first representative of them o-difluoromethoxybenzylideniminoxysilatrane (3) has been characterized by IR, 1H, 13C, 19F and 29Si NMR spectroscopy, mass-spectrometry, elemental and X-ray analyses. X-Ray crystallographic study indicates the presence of two independent molecules in the crystal with N → Si bond length of 2.073(6) and 2.088(5) A.
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CITATION STYLE
Lukevics, E., Ignatovich, L., Golomba, L., Popelis, J., & Belyakov, S. (2000). A new reaction of 1-hydrosilatrane. Main Group Metal Chemistry, 23(12), 761–764. https://doi.org/10.1515/MGMC.2000.23.12.761
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