Palladium nanoparticle array-mediated semiconductor bonding that enables high-efficiency multi-junction solar cells

Abstract

A detailed study on the application of Pd nanoparticle arrays, produced by self-assembled block copolymer templates, in bonding of III-V-based solar cell materials was carried out. The Pd nanoparticle array-mediated bonding (mechanical stacking) of GaAs-based thin-films (cells) was readily performed on the surface of GaAs or InP-based substrates (cells) to form multi-junction device architectures. Using the optimized Pd NP array, a 30.4%-efficiency four-junction two-terminal cell, consisting of an InGaP/GaAs top cell and an InGaAsP/InGaAs bottom cell, was achieved owing to the excellent electrical and optical bonding properties (bonding resistance, 1.81ωcm2; optical loss, 2.9%). Together with the verification of the long-term reliability of the Pd nanoparticle array-mediated bonding, our approach would become practically attractive for producing highefficiency multi-junction solar cells.