Analog of surface melting in a macroscopic nonequilibrium system

Abstract

Agitated wet granular matter can be considered as a nonequilibrium model system for phase transitions, where the macroscopic particles replace the molecules and the capillary bridges replace molecular bonds. It is demonstrated experimentally that a two-dimensional wet granular crystal driven far from thermal equilibrium melts from its free surface, preceded by an amorphous state. The transition into the surface melting state, as revealed by the bond orientational order parameters, behaves like a first order phase transition, with a threshold being traceable to the rupture energy of a single capillary bridge. The observation of such a transition in the macroscopic nonequilibrium system triggers the question of the universality of surface melting. © 2013 American Physical Society.