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Luminescent pro-nitroxide lanthanide complexes for the detection of reactive oxygen species

Chemical Communications (2020) 56(3) 435-438
DOI: 10.1039/c9cc06524e
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Abstract

The DOTA-based ligand H3L (5) appended with a pro-nitroxide moiety has been synthesized. The europium and ytterbium complexes 5Ln show metal-centred luminescence. They react with ROS in aqueous media to give a transient iminonitroxide and a stable nitronylnitroxide radical authenticated by EPR, with change in luminescence.

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Barré, R., Mouchel Dit Leguerrier, D., Fedele, L., Imbert, D., Molloy, J. K., & Thomas, F. (2020). Luminescent pro-nitroxide lanthanide complexes for the detection of reactive oxygen species. Chemical Communications, 56(3), 435–438. https://doi.org/10.1039/c9cc06524e

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