Abstract
The abrupt [HS-HS] ↔ localized [HS-LS] spin crossovers of a new triazole-based diiron(II) complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (ΔT = 22 K by SQUID magnetometer in "settle" mode) and show a remarkable scan rate dependence of only the cooling branch, as revealed by detailed magnetic, DSC, and Mössbauer studies. © 2014 American Chemical Society.
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CITATION STYLE
Kulmaczewski, R., Olguín, J., Kitchen, J. A., Feltham, H. L. C., Jameson, G. N. L., Tallon, J. L., & Brooker, S. (2014). Remarkable scan rate dependence for a highly constrained dinuclear iron(ii) spin crossover complex with a wide thermal hysteresis loop. Journal of the American Chemical Society, 136(3), 878–881. https://doi.org/10.1021/ja411563x
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