Abstract
Highly functionalized Grignard-reagents can be easily obtained by an iodine-magnesim exchange reaction and further reacted with various electrophiles. Via a B-Zn exchange reaction, a formal Michael addition with umpolung of the reactivity can be achieved. Chiral phosphine ligands can be easily synthesized by a 2.3 sigmatropic rearrangement and used successfully in asymmetric synthesis.
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CITATION STYLE
Knochel, P., Hupe, E., Dohle, W., Lindsay, D. M., Bonnet, V., Quéguiner, G., … Bunlaksananusorn, T. (2002). Functionalized main-group organometallics for organic synthesis. In Pure and Applied Chemistry (Vol. 74, pp. 11–17). Walter de Gruyter GmbH. https://doi.org/10.1351/pac200274010011
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