Multi-color luminescence and anticounterfeiting application of upconversion nanoparticle

Abstract

Multi-color luminescence materials are important in the illumination, solid-state three-dimensional display, information storage, biological labelling and anticounterfeiting fields. Herein, we designed a novel core-shell structure upconversion nanoparticle (UCNP) material (NaYF4) with lanthanide ion doping to achieve multi-color luminescence under a single NIR excitation laser. Different from the typical single-sensitizer materials, the core-shell structure utilizes Nd3+, Yb3+, Tm3+ and Er3+ ions to obtain tuning of the color and brightness. The doping of Nd3+ ions enhances the weak color (red) light source to maintain the light color balance. Benefiting from the color adjustment of the sensitizers and the change of the core-shell coating, bright-white emission and flexible color emission from red to green, cyan and blue can be achieved via the diverse doped rare earth ions in a single UCNP under continuous-wave laser excitation (980 nm). Simultaneously, the emission color of the UCNPs can change with the intensity of the excitation light source and the wavelength. The bright-white emission can be used for lighting displays, and the flexible full-color emission can be applied in the anticounterfeiting and information storage fields.