Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins-mechanistic considerations

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Abstract

We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.

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Sztorch, B., Frackowiak, D., & Marciniec, B. (2020). Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins-mechanistic considerations. Heterocyclic Communications, 26(1), 33–36. https://doi.org/10.1515/hc-2020-0006

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