Optimisation of arsenic (III) by colorimetric incorporated with image processing technique

Abstract

Inorganic arsenic contamination has caused a remarkable impact on the contamination of soil and groundwater in many countries. Consequently, determination of inorganic arsenic on site is very crucial especially arsenic (III) which is more toxic than arsenic (V). Thus, a more rapid, simple and ecofriendly approach was developed in this study to determine arsenic (III) by incorporation of image processing technique into colorimetric method. The effects of various factors were evaluated by a 24 full factorial design with a blocking factor. The mass ratio of sulfamic acid to zinc powder was the most significant factor affected red, green and blue (RGB) color values and followed by reaction period. The optimum conditions for the detection were found to be using 1 g of sulfamic acid and 0.5 g of zinc powder at 5 minutes. This work also demonstrates that the developed method is able to detect arsenic (III) rapidly and easily.