CO2 capture by a rhenium(I) complex with the aid of triethanolamine

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Abstract

A rhenium(I) tricarbonyl diimine complex with a N,N-dimethylformamide ligand captures one CO2 molecule in the presence of triethanolamine (TEOA), giving fac-[ReI(bpy)(CO)3{R2N-CH 2CH2O-COO}] (bpy = 2,2′-bipyridine, R = CH 2CH2OH). This could be a predominant complex in various photocatalytic CO2 reduction reactions using [ReI(N^N)(CO) 3X]n+ (N^N = diimine ligand; X = monodentate ligand; n = 0, 1) type complexes in the presence of TEOA. © 2013 American Chemical Society.

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Morimoto, T., Nakajima, T., Sawa, S., Nakanishi, R., Imori, D., & Ishitani, O. (2013). CO2 capture by a rhenium(I) complex with the aid of triethanolamine. Journal of the American Chemical Society, 135(45), 16825–16828. https://doi.org/10.1021/ja409271s

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