Synthesis and characterization of new 3-substituted thiophene copolymers

Abstract

This work reports the synthesis of three polymers and two new copolymers based on 3-substituted polythiophene derivatives, all of them demonstrated photoluminescent properties. All polymers synthesized, i.e., poly(3-methoxythiophene) (PMOT), poly(3-thiopheneethanol) (PTE), poly(3-thiophenemethanol) (PTM), poly(3-methoxythiophene-co-3-thiopheneethanol) (PMOT-co-TE) and poly(3-methoxythiophene-co-3-thiophenemethanol) (PMOT-co-TM), were characterized by FT IR, UV-Vis, photoluminescence (PL), thermal analysis (TG and DSC) and X-ray diffraction (XRD). All materials emitted light in the orange region of the visible spectrum. Spectrometric analysis in the infrared region demonstrated the successful synthesis of polymers and copolymers by the presence of characteristic bands. Thermal analysis showed that the obtained materials had good thermal stability. © 2011 Sociedade Brasileira de Química.