Photocatalytic activity of carbon nitride modified with a ruthenium(II) complex having carboxylic- or phosphonic acid anchoring groups for visible-light CO2 reduction

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Abstract

Semiconducting C3N4 powder modified with a catalytic Ru(II) complex having carboxylic acid groups as anchors showed higher activity for CO2 reduction into HCOOH under visible light (λ > 400 nm) at the initial stage of the reaction, whereas an analogue anchored with phosphonic acid groups exhibited higher stability.

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Maeda, K., Kuriki, R., & Ishitani, O. (2016). Photocatalytic activity of carbon nitride modified with a ruthenium(II) complex having carboxylic- or phosphonic acid anchoring groups for visible-light CO2 reduction. Chemistry Letters, 45(2), 182–184. https://doi.org/10.1246/cl.151061

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