1D Chains of Lanthanoid Ions and a Dithienylethene Ligand Showing Slow Relaxation of the Magnetization

Abstract

Three isostructural 1D lanthanoid complexes with the general formula {[Ln2(DTE)(H-DTE)(MeOH)2]·2H2O}n (Ln = Tb, Dy, and Yb; DTE = 1,2-bis(5-carboxyl-2-methyl-3-thienyl) perfluorocyclopentene) were synthesized. In the 1D chain structure of each complex, lanthanide ions are seven coordinate with a capped trigonal prism geometry. The 1,2-bis(5-carboxyl-2-methyl-3-thienyl) perfluorocyclopentene (DTE) ligand adopts a parallel configuration in these complexes, which results in the loss of the photo-isomerization ability of the ligand. From magnetic measurements, each complex undergoes slow relaxation of the magnetization via multiple processes in a dc field.