Preparation of Yttrium, Lanthanum, Cerium, and Neodymium Basic Carbonate Particles by Homogeneous Precipitation

Abstract

Uniform yttrium, lanthanum, cerium, and neodymium basic carbonate particles were prepared by homogeneous precipitation. Powders were characterized with respect to size, shape, crystal structure, and thermal decomposition behavior. Yttria precursor particles were spherical, monosized (0.4 μm), and amorphous; whereas lanthana, neodymia, and ceria precursors were prismatic (ranging from 1 to 6 μm in size) and crystalline. Crystal structure was found to be ancylite‐type orthorhombic symmetry in all three cases. Upon heating in air, yttrium, lanthanum, and neodymium precursors underwent two‐step decomposition to first form oxycarbonate and then oxide. Cerium hydroxycarbonate decomposed in a single step to form the oxide. 1987 The American Ceramic Society