Abstract
A mesoporous cationic Cr-MOF, termed FJI-C10, containing imidazolium moieties, Lewis acidic Cr3+ sites and free halogens is constructed for the first time by a topology-guided one-pot synthesis. FJI-C10 exhibits excellent performances in CO2 adsorption (20.2 wt% at 273 K and 1 bar) and chemical fixation of CO2 into cyclic carbonates without the use of co-catalyst under atmospheric pressure.
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CITATION STYLE
Liang, J., Xie, Y. Q., Wang, X. S., Wang, Q., Liu, T. T., Huang, Y. B., & Cao, R. (2018). An imidazolium-functionalized mesoporous cationic metal-organic framework for cooperative CO2 fixation into cyclic carbonate. Chemical Communications, 54(4), 342–345. https://doi.org/10.1039/c7cc08630j
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